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Zur Synthese von 3‐Desoxy‐aldulosonsäuren
Author(s) -
Baschang Gerhard,
Fritz Hans
Publication year - 1969
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19690520131
Subject(s) - chemistry , sodium salt , stereochemistry , derivative (finance) , medicinal chemistry , inorganic chemistry , financial economics , economics
Abstract The condensation of 2.4‐ethylidene‐erythrose with the sodium salt of diethyl‐phosphono‐piperidino‐ethylacetate yields an enamino‐lacton V which is converted under mild conditions into an α‐keto ester, 2‐oxo‐3‐desoxy‐gluconic acid, and its quinoxaline derivative.