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Die Kristallstruktur eines polynuclearen Silber‐Platin‐Mercaptophosphin‐Komplexes
Author(s) -
Strickler P.
Publication year - 1969
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19690520127
Subject(s) - chemistry , orthorhombic crystal system , diffractometer , crystallography , platinum , planar , crystal structure , atom (system on chip) , stereochemistry , biochemistry , computer graphics (images) , computer science , embedded system , catalysis
Crystals of Pt(S–CH 2 ‐Ch 2 ‐P(C 2 H 5 ) 2 ) 2 AgNO 3 are orthorhombic, a = 14.814, b = 10.926, c = 12.298 Å, space group Pbon , Z = 4. The structure has been solved by F OURIER methods and refined by full‐matrix least‐squares analysis of three dimensional intensity data, measured on the H ILGER & W ATTS computer‐controlled 4‐circle diffractometer. The structure consists of infinite chains running along the c ‐axis; each silver atom is coordinated almost linearly to two sulphur atoms belonging to the square‐planar coordination spheres of two different platinum atoms.