Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil I Entwicklung neuer Katalysatorsysteme auf der Basis von π‐Cyclobutadien‐Nickel(II)‐Verbindungen | Zendy

Onsager OlavTorgeir | Zendy; Wang Hagbarth | Zendy; Blindheim Ulf | Zendy

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Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil I Entwicklung neuer Katalysatorsysteme auf der Basis von π‐Cyclobutadien‐Nickel(II)‐Verbindungen

Author(s) -

Onsager OlavTorgeir,

Wang Hagbarth,

Blindheim Ulf

Publication year - 1969

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19690520119

Subject(s) - chemistry , nickel , catalysis , homogeneous , propene , aluminium , polymer chemistry , organic chemistry , physics , thermodynamics

Mixtures of π‐tetramethylcyclobutadiene‐nickeldihalides and L EWIS acids such as alkylaluminiumhalides in organic solvents represent new highly active homogeneous catalysts for the dimerization of ethylen, propene and butene under mild conditions. As a cocatalyst L EWIS bases may be used, in particular those containing trivalent phosphorous.

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