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Contribution à l'étude du système quaternaire KCI‐RbCI‐H 2 O: I. Les isothermes de 25° des systèmes ternaires limites
Author(s) -
Merbach A.,
Gonella J.
Publication year - 1969
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19690520107
Subject(s) - chemistry , miscibility , spinodal decomposition , limiting , ternary numeral system , ternary operation , thermodynamics , phase (matter) , physics , organic chemistry , mechanical engineering , engineering , polymer , computer science , programming language
The three ternary limiting isotherms of the system KCI‐RbCI‐CsCI‐H 2 O are given for 25°. The system KCI‐RbCI‐H 2 O, with only one solid phase present, belongs to the type I of the R OOZEBOOM classification. A large miscibility gap is present in the systems RbCI‐CsCI‐H 2 O and KCI‐CsCI‐H 2 O; in the latter the incorporation is almost negligible; they belong to R OOZEBOOM 's type IV.