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Herstellung und Eigenschaften von Oximen des 4‐Oxo‐4,5,6,7‐tetrahydroindols und ihre Umlagerung in Pyrrolo‐azepine 6. Mitteilung über synthetische Indol‐Verbindungen [1]
Author(s) -
Stoll André P.,
Troxler F.
Publication year - 1968
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19680510807
Subject(s) - chemistry , azepine , stereochemistry , medicinal chemistry
The preparation and B ECKMANN rearrangement of 4‐tosyloxyimino‐4,5,6,7‐tetrahydroindoles are described. The structures of the stereoisomeric parent oximes, their tosylates, and of the products of their B ECKMANN rearrangement have been confirmed by NMR and IR spectroscopy.