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Über die sensibilisierte Photooxydation einiger cyclischer N‐Aryl‐enamine. 3. Mitteilung über Indole, Indolenine und Indoline
Author(s) -
Pfoertner K.,
Bernauer Karl
Publication year - 1968
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19680510739
Subject(s) - chemistry , enamine , indoline , tautomer , quinoline , indole test , medicinal chemistry , aryl , stereochemistry , organic chemistry , catalysis , alkyl
Eosine‐sensitized photooxidation of the cyclic N‐aryl‐enamines 1 , 6 and 8 results in oxidative splitting of enamine double bonds. Thereby compounds 2 , 7 and 9 respectively are formed. From a mixture of the tautomeric quinoline derivatives 12 and 13 , on oxidation under similar conditions, the compounds 7 , 14 and 16 were isolated.