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Magneto‐optische Rotationsdispersion von gesättigten aliphatischen Kohlenwasserstoffen
Author(s) -
Wipf H.K.,
Clerc J. T.,
Simon W.
Publication year - 1968
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19680510506
Subject(s) - chemistry , magneto , wavelength , magneto optical , dispersion (optics) , analytical chemistry (journal) , computational chemistry , organic chemistry , optics , quantum mechanics , magnetic field , physics , combustion
Abstract Magneto‐optical rotatory dispersion (MORD.) of saturated aliphatic hydrocarbons can be described very accurately by an equation of the D RUDE type. The two parameters, appearing in such an equation, have been determined from MOR. measurements in the region of 240 to 500 nm by the method of least squares. These parameters show a systematic dependence on the structure of the investigated hydrocarbons. An empirical rule for the approximation of the D RUDE parameters is given which in turn allow the calculation of the V ERDET constant for a given structure at any wavelength between 240 and 500 nm.