Über En‐Synthesen mit Singulett‐Sauerstoff Die Farbstoff‐sensibilisierte Photooxygenierung von (−)‐Caryophyllen und (−)‐iso‐Caryophyllen und die Stereochemie der dargestellten Caryophylladienole | Zendy

SchulteElte K. H. | Zendy; Ohloff G. | Zendy

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Über En‐Synthesen mit Singulett‐Sauerstoff Die Farbstoff‐sensibilisierte Photooxygenierung von (−)‐Caryophyllen und (−)‐iso‐Caryophyllen und die Stereochemie der dargestellten Caryophylladienole

Author(s) -

SchulteElte K. H.,

Ohloff G.

Publication year - 1968

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19680510310

Subject(s) - chemistry , photooxygenation , medicinal chemistry , stereochemistry , organic chemistry , singlet oxygen , oxygen

The dye‐sensitized photooxygenation leads in the case of (−)‐caryophyllene ( 1 ) to 4 allylhydroperoxides, and with (−)‐iso‐caryophyllene ( 2 ) additionally to 2 tertiary compounds of this kind. The stereochemistry of the isolated 6 caryophylladienols derivatives 6 – 11 is elucidated. By that way an interpretation of the reaction mechanism is possible.

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