ESR.‐Spektrum des Radikal‐Anions des [ 18 ]Annulen‐1,4;7,10;13,16‐trisulfids | Zendy

Gerson F. | Zendy; Heinzer J. | Zendy

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ESR.‐Spektrum des Radikal‐Anions des [ 18 ]Annulen‐1,4;7,10;13,16‐trisulfids

Author(s) -

Gerson F.,

Heinzer J.

Publication year - 1968

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19680510215

Subject(s) - chemistry , annulene , coupling constant , ion , symmetry (geometry) , crystallography , stereochemistry , computational chemistry , medicinal chemistry , organic chemistry , physics , geometry , mathematics , particle physics

The ESR spectrum of the radical‐anion of [ 18 ]annulene‐1,4;7,10;13,16‐trisulfide (ATS) has been recorded. Its analysis yields six coupling constants for pair of equivalent protons indicating the lack of a threefold symmetry axis. A provisional assignment has been attempted which is based on calculated spinpopulations. Conformations of ATS and ATS ⊖ are shortly discussed.

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