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Sythese von α und β‐Sinensal
Author(s) -
Bertele E.,
Schudel P.
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500830
Subject(s) - phosphorane , chemistry , methylene , aldehyde , stereochemistry , medicinal chemistry , organic chemistry , catalysis
β‐Sinensal (2,6‐dimethyl‐10‐methylene‐dodeca‐2,6,11‐trienal) was synthesized from the diene‐aldehyde 5 . This was converted into the trans ‐ and cis ‐triene‐aldehydes 16 and 17 , which were condensed with the phosphorane 18 to give the corresponding two geometrical isomers ( 3 and 19 ) of β‐sinensal.