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Die Cardenolide von Acokanthera oppositifolia (LAM.) CODD. 3. Mitteilung . Isolierung weitere Cardenolide und teilweise Strukturaufklärung. Glykoside und Aglykone, 301. Mitt.
Author(s) -
Hauschildrogat P.,
Weiss E. K.,
Reichstein T.
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500815
Subject(s) - chemistry , cardenolide , stereochemistry , glycoside
The presence of 19 cardenolides in the extracts from the seeds of Acokanthear oppositifolia (Lam.) CODD could be traced by means of paper chromatography. Thirteen of these cardenolides could be isolated in crystalline form, acovenoside A (= 2) being by far the major component. Of the other 12 crystalline substances, 5 could be identified with known cardenolides: 2′ = acofrioside L, 3 = acolongifloroside H, 14 = acovenoside C, 15 = acolongifloroside K, 16 = ouabain. The substances 1′, 1″, 4, 6, 7, 8 and 13 are very probably new compounds. Four of these were given trivial names and the following structures were proposed: 1″ = oppovenoside, probably 10 ; 4 = oppofrioside ( 5 ); 6 = acotaloside ( 6 ); 13 = opposide, probably 12 , cf. following publication [21]. Furthermore, the structure 8 has been proposed for acolongifloroside H.