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Darstellung und Charakterisierung einige Thiocyanat‐ und Selenocyanat‐Komplexe von Übergangsmetallen
Author(s) -
Schmidtke HansHerbert,
Garthoff Dieter
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500622
Subject(s) - chemistry , thiocyanate , linkage isomerism , medicinal chemistry , ligand (biochemistry) , stereochemistry , inorganic chemistry , metal , organic chemistry , receptor , biochemistry
Some 6:1 thiocyanate complexes of Fe III , Mo III , Ru III , Os III , Ir III and some 6:1 or 4:1 selenocyanate complexes of Fe II , Fe III , Mo III , Rh III , Pd II , Pt II , and Au III have been prepared as salts of large organic cations. The compounds are characterized by their infra‐red spectra and by conductance measurements. In particular the linkage property of the thiocyanate and selenocyanate ligand is discussed together with the consequences it has on the A HRLAND ‐C HATT ‐D AVIES ‐P EARSON classification of the central ions.