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Etude sur les composés organométalliques III [1]. Action d'organomagnésiens sur des complexes du tétrachlorure de titane
Author(s) -
Boustany Kamel S.,
Bernauer Klaus,
JacotGuillarmod André
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500513
Subject(s) - chemistry , yield (engineering) , medicinal chemistry , piperidine , titanium , pyridine , molar ratio , ligand (biochemistry) , stereochemistry , organic chemistry , catalysis , receptor , biochemistry , materials science , metallurgy
The reaction between RM g X and TiCl 4 ,2L (L = pyridine, piperidine or quinoleine) is shown to give a high yield of organo‐titanium (IV) compounds. As expected, the decomposition of the latter is reduced to a minimum by the ligand L initially present, allowing the preparation of etheral solutions of R 4 Ti (R = benzyl, phenyl or butyl). R 4 Ti is obtained whatever may be the initial molar ratio of RM g X/TiCl 4 , 2L.