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Etudes sur les composés organométalliques I action du chlorure de benzylmagnésium et du bromure de phénylmagnésium sur le tétrachlorure de titane
Author(s) -
Boustany Kamel S.,
Bernauer Klaus,
JacotGuillarmod André
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500414
Subject(s) - chemistry , titanium tetrachloride , medicinal chemistry , phenylmagnesium bromide , bromide , reagent , titanium , organic chemistry
The reactions between phenylmagnesium bromide or benzylmagnesium chloride and titanium tetrachloride have been studied. The influence of the introduction order of the reagents is mentioned. Decomposition of the (non‐isolated) compounds R n TiX 4‐n is shown to be essentially intermolecular, and rarely intramolecular.