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Magnetische Kernresonanz‐ und «Molecular Orbital»‐ untersuchungen über die struktur von M EISENHEIMER ‐komplexen 8. Mitteilung über nucleophile aromatische Substitutionsreaktionen [1]
Author(s) -
Caveng P.,
Fischer P. B.,
Heilbronner E.,
Miller A. L.,
Zollinger H.
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500312
Subject(s) - chemistry , nucleophile , intramolecular force , methoxide , medicinal chemistry , stereochemistry , methanol , organic chemistry , catalysis
(1) The NMR. spectra of the stable methoxide addition complexes of 2,4‐dinitro‐, 2,4,6‐trinitro‐ and 2,4‐dinitro‐6‐cyano‐anisole, and the intramolecular (spiro) reaction product of 1‐(2′‐hydroxyethoxy)‐2,4,6‐trinitrobenzene demonstrate that these products are M EISENHEIMER (σ−) complexes (addition of base in position 1).