Magnetische Kernresonanz‐ und «Molecular Orbital»‐ untersuchungen über die struktur von M EISENHEIMER ‐komplexen 8. Mitteilung über nucleophile aromatische Substitutionsreaktionen [1] | Zendy

Caveng P. | Zendy; Fischer P. B. | Zendy; Heilbronner E. | Zendy; Miller A. L. | Zendy; Zollinger H. | Zendy

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Magnetische Kernresonanz‐ und «Molecular Orbital»‐ untersuchungen über die struktur von M EISENHEIMER ‐komplexen 8. Mitteilung über nucleophile aromatische Substitutionsreaktionen [1]

Author(s) -

Caveng P.,

Fischer P. B.,

Heilbronner E.,

Miller A. L.,

Zollinger H.

Publication year - 1967

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19670500312

Subject(s) - chemistry , nucleophile , intramolecular force , methoxide , medicinal chemistry , stereochemistry , methanol , organic chemistry , catalysis

(1) The NMR. spectra of the stable methoxide addition complexes of 2,4‐dinitro‐, 2,4,6‐trinitro‐ and 2,4‐dinitro‐6‐cyano‐anisole, and the intramolecular (spiro) reaction product of 1‐(2′‐hydroxyethoxy)‐2,4,6‐trinitrobenzene demonstrate that these products are M EISENHEIMER (σ−) complexes (addition of base in position 1).

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