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Die sterischen Bedingungen der Fragmentierungsreaktion III. Teil. Stereoisomere 4‐, 5‐ und 7‐Decahydrochinolyl‐toluolsulfonate Fragmentierungsreaktionen, 16. Mitteilung
Author(s) -
Grob C. A.,
Kiefer H. R.,
Lutz H. J.,
Wilkens H. J.
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500211
Subject(s) - chemistry , heterolysis , solvolysis , medicinal chemistry , stereochemistry , fragmentation (computing) , organic chemistry , catalysis , hydrolysis , computer science , operating system
In a heterolytic fragmentation reaction of the type a‐b‐c‐d‐X → a ‐ b + c = d + : X the geometry of the d ‐ X bond and that of the electron‐donating group a relative to the b ‐ c bond are critical. This follows from a study of solvolysis rates and products of stereoisomeric 1‐methyl‐4‐, ‐5‐ and ‐7‐decahydroquinolyl p ‐toluenesulphonates in 80 Vol.% ethanol.