Die sterischen Bedingungen der Fragmentierungsreaktion III. Teil. Stereoisomere 4‐, 5‐ und 7‐Decahydrochinolyl‐toluolsulfonate Fragmentierungsreaktionen, 16. Mitteilung | Zendy

Grob C. A. | Zendy; Kiefer H. R. | Zendy; Lutz H. J. | Zendy; Wilkens H. J. | Zendy

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Die sterischen Bedingungen der Fragmentierungsreaktion III. Teil. Stereoisomere 4‐, 5‐ und 7‐Decahydrochinolyl‐toluolsulfonate Fragmentierungsreaktionen, 16. Mitteilung

Author(s) -

Grob C. A.,

Kiefer H. R.,

Lutz H. J.,

Wilkens H. J.

Publication year - 1967

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19670500211

Subject(s) - chemistry , heterolysis , solvolysis , medicinal chemistry , stereochemistry , fragmentation (computing) , organic chemistry , catalysis , hydrolysis , computer science , operating system

In a heterolytic fragmentation reaction of the type a‐b‐c‐d‐X → a ‐ b + c = d + : X the geometry of the d ‐ X bond and that of the electron‐donating group a relative to the b ‐ c bond are critical. This follows from a study of solvolysis rates and products of stereoisomeric 1‐methyl‐4‐, ‐5‐ and ‐7‐decahydroquinolyl p ‐toluenesulphonates in 80 Vol.% ethanol.

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