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Optische Rotationsdispersion von Indolalkaloiden der Yohimban‐, Corynanthean‐ und Quebrachamin‐Gruppe
Author(s) -
Klyne W.,
Swan R. J.,
Dastoor N. J.,
Gorman A. A.,
Schmid H.
Publication year - 1967
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19670500118
Subject(s) - chemistry , optical rotatory dispersion , chromophore , stereochemistry , organic chemistry , circular dichroism
It has been shown that optical rotatory dispersion curves can be used to determin‐ the absolute stereochemistry at C(3) of indole alkaloids of the yohimban and corynane thean types. This is dependent on the absence of strong chromophores other than that of the aromatic system.