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Nickel‐ und Palladiumkomplexe mit Phosphinothioäthern
Author(s) -
Degischer G.,
Schwarzenbach G.
Publication year - 1966
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19660490629
Subject(s) - chemistry , ligand (biochemistry) , nickel , halogen , sulfide , medicinal chemistry , metal , polymer chemistry , stereochemistry , organic chemistry , biochemistry , alkyl , receptor
A new terdentate ligand bis‐(diphenylphosphinoethyl)‐sulfide (PSP) and a new quadridentate ligand 1, 2‐bis‐(diphenylphosphinoethylthio)‐ethane (PSSP) (structures see page 1928) have been synthesized and their Ni II ‐ and Pd II ‐complexes have been studied. There is good evidence that the metal has coordination number five in some of these complexes containing halogen (Cl, Br, J).