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Über Struktur und Aktivität der den H 2 O 2 ‐Zerfall katalysierenden Cu 2+ ‐Komplexe. V. Vergleich der katalytischen Aktivität der Cu 2+ ‐Komplexe isomerer β‐Hydroxythiophen‐Derivate. Mettallionen und H 2 O 2 , 9. Mitteilung
Author(s) -
Petri S.,
Sigel H.,
Erlenmeyer H.
Publication year - 1966
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19660490611
Subject(s) - chemistry , thiophene , medicinal chemistry , catalysis , chelation , decomposition , ring (chemistry) , stereochemistry , organic chemistry
Abstract The catalytic properties in H 2 O 2 decomposition of the Cu 2+ ‐chelates of 2‐ Acetyl‐3‐hydroxy‐thiophene (I) and 3‐Acetyl‐4‐hydroxy‐thiophene (II) have been investigated. Evidence is given that the catalytic activity of the chelates is a function of the respective bond orders of the α, β (I) and β, β′ (II) thiophene bonds of the chelate ring.