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Zum Zusammenhang zwischen Ligand‐Acidität und Metallkomplex‐Stabilität: Abnehmende Stabilität bei zunehmender Basizität
Author(s) -
Sigel H.,
Kaden Th.
Publication year - 1966
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19660490522
Subject(s) - chemistry , ligand (biochemistry) , medicinal chemistry , stereochemistry , receptor , biochemistry
The increase of the stability of metal ion complexes with decreasing basicity of the ligands within different series is discussed with the help of the equation of I RVING & R OSSOTTI [4] [12] and explained in terms of the free energy G MeL 0of the complexes.