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Die Reaktion von Isonitrilen und Nitrilen mit Alkali‐ und Erdalkalimetallen
Author(s) -
Büchner W.,
Dufaux R.
Publication year - 1966
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19660490312
Subject(s) - chemistry , carbanion , alkali metal , liquid ammonia , ammonia , medicinal chemistry , organic chemistry
Isocyanides RNC and the isomeric nitriles, RCN, reacting with alkali or alkaline earth metals in liquid ammonia undergo reductive fission to metal cyanides and carbanions R − . The latter are ammonolized to the corresponding hydrocarbons.