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Ermittlung der absoluten Konfiguration von Indolinalkaloiden durch Vergleiche der Optischen Rotationsdispersionen ihrer N(a)‐Acylderivate
Author(s) -
Klyne W.,
Swan R. J.,
Bycroft B. W.,
Schmid H.
Publication year - 1966
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19660490202
Subject(s) - chemistry , absolute configuration , optical rotatory dispersion , stereochemistry , chromophore , organic chemistry , circular dichroism
A further application of Optical Rotatory Dispersion (ORD) for indole alkaloids containing an N‐acylindoline chromophore has completely substantiated an earlier assignment of the absolute configuration of Aspidosperma alkaloids and has extended the general scope of this method, allowing assignments to the absolute configuration of N(a)‐acetyl‐aspidospermatidine and limatine.