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Komplexone XXXVIII . Reaktionsenthalpie und ‐entropie bei der Bildung der 1:1‐und 1:2‐Metallkomplexe von Methyliminodiessigsäure
Author(s) -
Anderegg G.
Publication year - 1965
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19650480731
Subject(s) - chemistry , enthalpy , chelation , medicinal chemistry , inorganic chemistry , thermodynamics , physics
The enthalpy changes involved in the metal complex formation with methyliminodiacetate‐ion have been determined, using a direct calorimetric method. The thermodynamic data obtained are used to calculate the chelate effect with the EDTA‐homologous ( − OOCCH 2 ) 2 = N(CH 2 ) n N = (CH 2 COO − ) 2 as ligand.
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