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Peroxidbildung bei der Autoxydation N 2 ‐substituierter Methylhydrazine
Author(s) -
Aebi H.,
Dewald Beatrice,
Suter Hedi
Publication year - 1965
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19650480619
Subject(s) - chemistry , methylhydrazine , autoxidation , methemoglobin , medicinal chemistry , formate , peroxide , organic chemistry , hemoglobin , catalysis , phenylhydrazine
1. Formation of peroxide as produced in autoxidation of N 2 ‐substituted methylhydrazine derivatives has been studied with the W ARBURG technique. The following methods for its detection have been used: (a) chemical and enzymatic estimation of H 2 O 2 , (b) coupled formate oxidation (H 14 COONa → 14 CO 2 ), (c) methemoglobin formation in suspensions of acatalatic red cells as a «biological indicator».