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Konstellation und Solvolysegeschwindigkeit der 1‐Decalyl‐ p ‐toluolsulfonate
Author(s) -
Grob C. A.,
Tam S. W.
Publication year - 1965
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19650480612
Subject(s) - chemistry , stereochemistry
The NMR.‐spectra of the four 1‐decalols and of their p ‐toluenesulfonates have been determined. They are in agreement with accepted configurational assignments. Low‐temperature NMR.‐spectra of the cis ‐1‐decalols indicate the predominance of conformation 7a in the case of the cis ‐ cis isomer m.p. 93° and a conformational equilibrium 8a ⇄ 8b in the case of the cis ‐ trans isomer m.p. 55°.
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