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Reaktivität von Koordinationsverbindungen XIV. Reversible O 2 ‐Bindung an Eisen(II)‐Phtalocyanintetrasulfonsäure
Author(s) -
Vonderschmitt D.,
Bernauer Klaus,
Fallab S.
Publication year - 1965
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19650480432
Subject(s) - chemistry , oxidation state , redox , oxygen , medicinal chemistry , solid state , inorganic chemistry , crystallography , metal , organic chemistry
Oxidation and reduction properties of iron(II) and iron(III) phthalocyaninetetrasulphonic‐acids are described. The reversible reaction of the iron(II) compound with molecular oxygen leads to a binuclear complex Fe II · O 2 · Fe II . At a neutral pH no oxidation to the iron(III) state occurs. The stability of the O 2 ‐complex has been determined.
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