Reaktivität von Koordinationsverbindungen XIII. Zum Mechanismus der Eisen(II)‐katalysierten Autoxydation eines Formazanfarbstoffes | Zendy

Trefzer K. | Zendy; Fallab S. | Zendy

Premium

Reaktivität von Koordinationsverbindungen XIII. Zum Mechanismus der Eisen(II)‐katalysierten Autoxydation eines Formazanfarbstoffes

Author(s) -

Trefzer K.,

Fallab S.

Publication year - 1965

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19650480431

Subject(s) - chemistry , autoxidation , electron transfer , kinetics , ternary operation , ternary complex , ligand (biochemistry) , medicinal chemistry , photochemistry , organic chemistry , receptor , biochemistry , physics , enzyme , quantum mechanics , computer science , programming language

The kinetics and the mechanism of the Fe 2+ catalysed autoxidation of a chelate forming formazyl derivative have been studied. Inhibition by CN − suggests formation of a ternary complex with O 2 as a reactive intermediate in which oxidation takes place via electron transfer without formation of an iron(III)‐compound. The Fe 2+ keeps the reactants in a favourable position and provides suitable orbitals for the electron transfer from the ligand to the O 2 ‐molecule.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research