Premium
Zur Kenntnis der Hexaalkylbenzole. 7. Mitteilung. Anomale F RIEDEL ‐C RAFTS ‐Reaktionen von Hexa‐ n ‐propylbenzol
Author(s) -
Hopff H.,
Gati A.
Publication year - 1965
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19650480322
Subject(s) - chemistry , hexa , benzamide , hydrolysis , medicinal chemistry , benzoic acid , alkyl , benzene , stereochemistry , organic chemistry
Hexa‐ n ‐propylbenzene undergoes the same anomalous type of F RIEDEL ‐C RAFTS reactions as hexaethyl and hexamethyl benzene. Acid chlorides and dicarboxylic anhydrides produce under elimination of an alkyl group the corresponding penta‐ n ‐propyl‐phenyl ketones and penta‐ n ‐propyl‐benzoyl carboxylic acids respectively. Reaction of the carbamylchloride‐aluminiumchloride complex yields penta‐ n ‐propyl‐benzamide which has been hydrolysed to penta‐ n ‐propyl‐benzoic acid.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom