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Étude de composés d'addition des acides de L EWIS XXII . Échange du chlore radioactif entre AlCl 3 et C 6 H 5 COCl
Author(s) -
Oulevey G.,
Susz B. P.
Publication year - 1964
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19640470719
Subject(s) - chemistry , chlorine , nuclear chemistry , medicinal chemistry , organic chemistry
A method of studying the exchange of chlorine between C 6 H 5 COCl and AlCl 3 labelled with 36 Cl has been worked out. It consists of removing rapidly C 6 H 5 COCl from the addition compound C 6 H 5 COCl, Al[ 36 Cl] 3 , formed in CS 2 with p ‐dioxane, which in its turn gives an addition compound p ‐dioxane,AlCl 3 . The latter compound described by the authors is stable enough to be easily isolated and lends itself well for the measure of the radioactivity of 36 Cl.