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Metallionen‐Katalyse bei der H 2 O 2 ‐ bzw. Radikal‐Bildung durch autoxydable Cytostatica. III. Ligand‐Effekte
Author(s) -
Brintzinger H.,
Zell R.,
Erlenmeyer H.
Publication year - 1964
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19640470628
Subject(s) - chemistry , autoxidation , hydrazine (antidepressant) , manganese , catalysis , ligand (biochemistry) , medicinal chemistry , polymer chemistry , organic chemistry , receptor , chromatography , biochemistry
The effect of various ligands on Mn 2+ ‐catalysed radical and H 2 O 2 , formation by autoxidation of cytostatic hydrazine derivatives has been investigated. The catalytic action is activated by ligands which favour formation of the tervalent state of manganese ion. This finding is discussed in terms of possible mechanisms.