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Einfluss der γ‐Verzweigung auf Solvolysegeschwindigkeit und Fragmentierung von Alkyl‐ und Cycloalkyl‐Halogeniden und ‐Arylsulfonaten. Fragmentierungsreaktionen, 8. Mitteilung
Author(s) -
Grob C. A.,
Schwarz W.,
Fischer H. P.
Publication year - 1964
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19640470602
Subject(s) - chemistry , medicinal chemistry , solvolysis , octane , alkyl , isopropyl , bicyclic molecule , halide , organic chemistry , hydrolysis
In an investigation on the effect of branching in the γ‐position of alkyl and cycloalkyl halides and arylsulfonates the solvolysis rates and products of cis ‐ and trans ‐3,3,5‐trimethylcyclohexyl tosylate ( 18 ) and ( 19 ), 1‐bromo‐ and 1‐bromo‐3,3‐dimethyl‐bicyclo[2.2.2]octane ( 20a and b ), 1‐bromo‐adamantane ( 21a ) and its 3‐methyl, 3‐ethyl, 3‐isopropyl and 3,5,7‐trimethyl derivatives ( 21b , c , d ) and ( 22 ), respectively, have been determined.