Photochemische Reaktionen 29. Mitteilung [1]  Zum Mechanismus der photochemischen Umlagerung von 3‐Oxo‐4,5‐oxido‐Steroiden (Vorläufige Mitteilung) | Zendy

Wehrli H. | Zendy; Lehmann C. | Zendy; Schaffner K. | Zendy; Jeger O. | Zendy

Premium

Photochemische Reaktionen 29. Mitteilung [1] Zum Mechanismus der photochemischen Umlagerung von 3‐Oxo‐4,5‐oxido‐Steroiden (Vorläufige Mitteilung)

Author(s) -

Wehrli H.,

Lehmann C.,

Schaffner K.,

Jeger O.

Publication year - 1964

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19640470528

Subject(s) - chemistry , stereospecificity , medicinal chemistry , stereochemistry , organic chemistry , catalysis

3‐Oxo‐4,5‐oxido‐10β‐steroids have previously been shown to rearrange photolytically to the corresponding 3,5‐dioxo‐10(5 → 4)‐ abeo compounds (cf. a, b → c ). According to the present findings, the 10α‐testosterone oxide 4 gives specifically the l0α‐product 5 and the stereoisomeric 4‐methyl‐testosterone oxides 8 and 10 undergo stereospecific rearrangements to the products 11 and 12 respectively.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research