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Über π‐Allyl‐acyl‐Eisencarbonyl‐Verbindungen
Author(s) -
Murdoch H. D.
Publication year - 1964
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19640470403
Subject(s) - chemistry , allylic rearrangement , allyl alcohol , organic chemistry , medicinal chemistry , catalysis
The reactions of allylic diols or allylic chloro‐alcohols with di‐iron‐enneacarbonyl give, by elimination of water or HCL, π‐allyl‐acyl‐iron‐tricarbonyl complexes. The structures of these products are discussed on the basis of spectroscopic and chemical studies.