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Phtalocyanine in wässeriger Lösung IV. Kinetik und Mechanismus der Metallkomplexbildung
Author(s) -
Schiller I.,
Bernauer Klaus
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460758
Subject(s) - chemistry , dissociation (chemistry) , phthalocyanine , pyrrole , metal , medicinal chemistry , ligand (biochemistry) , photochemistry , ion , polymer chemistry , organic chemistry , biochemistry , receptor
Abstract The mechanism of metal ion incorporation into phthalocyanine tetrasulfonic acid has been investigated. The rate determining step of these reactions is the pyrrole‐NH‐dissociation of the ligand, which is catalysed by particles like MeOH + .