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Reaktionen von Steroid‐Hypojoditen VII. 3‐Oxo‐1,11α‐oxido‐Δ 1 ‐steroide. Über Steroide, 204. Mitteilung
Author(s) -
Meystre Ch.,
Kalvoda J.,
Anner G.,
Wettstein A.
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460742
Subject(s) - chemistry , steroid , enol , stereochemistry , homolysis , cleavage (geology) , medicinal chemistry , organic chemistry , hormone , catalysis , biochemistry , radical , geotechnical engineering , fracture (geology) , engineering
The homolytic cleavage of 11‐hypoiodites of 3‐oxo‐11α‐hydroxy‐steroids, generated from the corresponding hydroxy compounds by treatment with lead tetraacetate and iodine, has been investigated. The main reaction products are enol ethers containing the 3‐oxo‐1, 11α‐oxido‐Δ 1 ‐grouping.