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Solvolyse von 2‐(α‐Chlorbenzyl)‐chinuclidin. Zur Kenntnis der Heterocinchonin‐Umlagerung. Chinuclidin‐Reihe, 7. Mitteilung
Author(s) -
Braschler V.,
Grob C. A.,
Kaiser A.
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460723
Subject(s) - chemistry , quinuclidine , cinchonine , medicinal chemistry , organic chemistry , catalysis , enantioselective synthesis
Reaction rate and hydrolysis products of 2‐(α‐chlorobenzyl)‐quinuclidine (13b) provide no evidence for the participation of the quinuclidine nitrogen in the ionisation step of this unusual β‐haloamine. Furthermore, no product derived from a «hetero‐cinchonine rearrangement» was isolated.