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Photochemische Reaktionen. 24. Mitteilung. Die UV.‐Bestrahlung von Testosteron und 3‐Oxo‐17β‐acetoxy‐Δ 1;5 ‐androstadien. (Vorläufige Mitteilung)
Author(s) -
Nann B.,
Gravel D.,
Schorta R.,
Wehrli H.,
Schaffner K.,
Jeger O.
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460702
Subject(s) - chemistry , stereospecificity , solvent , reactivity (psychology) , steroid , medicinal chemistry , photochemistry , stereochemistry , organic chemistry , hormone , catalysis , biochemistry , medicine , alternative medicine , pathology
1. The photochemical reactivity of testosterone ( 1 ) is strongly influenced by the nature of the solvent. Dimerization (→ 18 ), pinacone formation (→ 19 )), reactions between the steroid and the solvent molecules (→ 20a , 20b , 21 ) and stereospecific isomerizations (→ 2 , 4 ) are observed.