Premium
Reaktivität von Koordinationsverbindungen IX. Zur Bildung von binuclearen μ‐peroxo‐Kobaltkomplexen
Author(s) -
Bekâroğlu Oezer,
Fallab S.
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460630
Subject(s) - chemistry , chelation , ligand (biochemistry) , polymer chemistry , medicinal chemistry , inorganic chemistry , receptor , biochemistry
The tendency of Co II ‐chelates to form binuclear μ‐peroxo‐bridged complexes with O 2 has been investigated. The nature of the ligand strongly influences the stability of such complexes. Polyamin chelates obviously fovour the bonding to O 2 whereas chelates with aminopolycarboxylic acids do not show any measurable affinity for O 2 . The solution stability of (Dien)CoO 2 Co(Dien) 4+ has been determined by spectrophotometric methods.