Reaktivität von Koordinationsverbindungen IX. Zur Bildung von binuclearen μ‐peroxo‐Kobaltkomplexen | Zendy

Bekâroğlu Oezer | Zendy; Fallab S. | Zendy

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Reaktivität von Koordinationsverbindungen IX. Zur Bildung von binuclearen μ‐peroxo‐Kobaltkomplexen

Author(s) -

Bekâroğlu Oezer,

Fallab S.

Publication year - 1963

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19630460630

Subject(s) - chemistry , chelation , ligand (biochemistry) , polymer chemistry , medicinal chemistry , inorganic chemistry , receptor , biochemistry

The tendency of Co II ‐chelates to form binuclear μ‐peroxo‐bridged complexes with O 2 has been investigated. The nature of the ligand strongly influences the stability of such complexes. Polyamin chelates obviously fovour the bonding to O 2 whereas chelates with aminopolycarboxylic acids do not show any measurable affinity for O 2 . The solution stability of (Dien)CoO 2 Co(Dien) 4+ has been determined by spectrophotometric methods.

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