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La déshydratation du trichlorométhyl–2‐butanol‐2
Author(s) -
Thomas A. F.,
Palluy E.,
Willhalm B.,
Stoll M.
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460626
Subject(s) - chemistry , dehydration , medicinal chemistry , butanol , product (mathematics) , organic chemistry , ethanol , biochemistry , geometry , mathematics
Abstract The dehydration products of 2‐trichloromethyl–2‐butanol are the 2‐trichloro‐methyl–1‐and ‐2‐butenes. The first of these easily rearranges to 1, 1‐dichloro‐2‐chloro‐methyl‐1‐butene, but the allyl rearrangement product from the other is highly reactive, and gives further transformation products under the conditions used for the rearrangement.