Premium
Elektronenspektrum und Basizität des Cycl[3.2.2]azins
Author(s) -
Gerson F.,
Heilbronner E.,
Joop N.,
Zimmermann H.
Publication year - 1963
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19630460611
Subject(s) - chemistry , crystallography , stereochemistry
From theoretical predictions based on MO models together with the experimental polarization directions, the first four absorption bands of the UV. spectrum of cycl[3.2.2]azin ( I ) have been assigned to the following electronic transitions (in order of increasing energy): a) 1 A → 1 L b , (B 2 ); b) 1 A → 1 L a , (A 1 ); c) 1 A → 1 B a , (A 1 ); d) 1 A → 1 B b , (B 2 .