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Recherches sur la formation et la transformation des esters XXXIX. Sur la phosphonylation des hydroxynitriles par l'oxyde phénylphosphonique
Author(s) -
Cherbuliez Emile,
Hunkeler F.,
Rabinowitz J.
Publication year - 1962
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19620450738
Subject(s) - chemistry , yield (engineering) , polymer chemistry , oxide , medicinal chemistry , organic chemistry , composite material , materials science
The phosphonylation of cyano alcohols by means of phenylphosphonic oxide is described. α‐Cyano alcohols yield exclusively the corresponding α‐carbamidoalkyl phenylphosphonic monoesters, β‐cyano alcohols yield mainly the corresponding β‐cyanoalkyl phenylphosphonic monoesters, and γ‐ and δ‐cyano alcohols yield exclusively the corresponding γ and δ‐cyanoalkyl phenylphosphonic monoesters.