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Photochemische Reaktionen. 16. Mitteilung. Photochemische Umwandlungen von O‐Acetyl‐1‐dehydrotestosteron I
Author(s) -
Dutler H.,
Ganter C.,
Ryf H.,
Utzinger E. C.,
Weinberg K.,
Schaffner K.,
Arigoni D.,
Jeger O.
Publication year - 1962
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19620450708
Subject(s) - chemistry , phenols , medicinal chemistry , phenol , stereochemistry , organic chemistry
UV.‐irradiation of O‐acetyl‐1‐dehydro‐testosterone in dioxane solution yields a mixture of photo‐isomers from which four phenolic and five ketonic components have been isolated. Two of the phenols have been identified as the known 17‐O‐acetyl‐1‐methyl‐estradiol and 1‐hydroxy‐17β‐acetoxy‐4‐methyl‐δ 1;3;5,10 ‐estratriene. The constitutions of the two remaining phenols and of four of the ketones have been elucidated.