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Solvolyse von γ‐Aminoalkylhalogeniden II. Teil. Fragmentierungsreaktionen. 2. Mitteilung
Author(s) -
Grob C. A.,
Ostermayer F.,
Raudenbusch W.
Publication year - 1962
Publication title -
helvetica chimica acta
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19620450534
Subject(s) - chemistry , solvolysis , medicinal chemistry , fragmentation (computing) , halide , organic chemistry , hydrolysis , computer science , operating system
α,α‐Dimethyl γ‐dimethylaminoalkyl halides Me 2 NCH 2 CMe 2 X (X = Cl, Br, I) undergo fragmentation (43–47%) upon solvolysis in «80%» ethanol. The relative rates at 40° are 1, 38 and 113.