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Butadien‐Eisencarbonyl‐Verbindungen
Author(s) -
Murdoch H. D.,
Weiss E.
Publication year - 1962
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19620450412
Subject(s) - chemistry , cationic polymerization , olefin fiber , polar , hydrogen chloride , chloride , polymer chemistry , iron(iii) chloride , photochemistry , medicinal chemistry , organic chemistry , catalysis , physics , astronomy
Abstract The preparation of two new π‐olefin complexes, butadiene iron tetracarbonyl and butadiene di‐iron octacarbonyl, is described and their structures are discussed. Butadiene iron tetracarbonyl adds hydrogen chloride with formation of an unstable cationic complex which decomposes easily, especially in polar solvents, with formation of π‐methallyl iron tricarbonyl chloride.