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Über Steroide und Sexualhormone. 224. Mitteilung. Die Umsetzung von 3α‐Hydroxy‐5β‐Steroiden mit Blei(IV)‐acetat
Author(s) -
Immer H.,
Mihailović M. Lj.,
Schaffner K.,
Arigoni D.,
Jeger O.
Publication year - 1962
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19620450304
Subject(s) - chemistry , medicinal chemistry
Treatment of different 3α‐hydroxy‐5β‐steroids with lead tetraacetate leads to the formation of 3α, 9‐oxido derivatives in yields that are strongly dependent on the nature of ring C. The significance of these reactions with regard to the mechanism of the lead tetraacetate oxidation of monohydric alcohols is discussed.