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Etudes sur les matières végétales volatiles CLXXIX. Synthèses des cis ‐ et trans ‐[méthyl‐2‐propène‐1]‐yl‐2‐méthyl‐4‐tétrahydropyrannes
Author(s) -
Naves YvesRené,
Tullen Paul
Publication year - 1961
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19610440705
Subject(s) - chemistry , medicinal chemistry , diene , stereochemistry , organic chemistry , natural rubber
Reduction of the hydroperoxides prepared by oxygenation of (+)‐β‐citronellyl acetate affords the acetate of (+)‐2,3‐epoxy‐dihydrocitronellol and the acetates of the (+)‐dehydrocitronellols (the (+)‐2,6‐dimethyl‐octa‐1,3‐diene‐8‐ols predominating in the latter), as well as those of the (+)‐2,6‐dimethyl‐oct‐3‐ene‐2,8‐diols (where the trans ‐ isomer predominates).