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Étude de composés d'addition des acides de L EWIS XVII. Synthèse cétonique de Friedel & C RAFTS en présence de chlorure d'aluminium radioactif marqué par 36 Cl 1 )
Author(s) -
Oulevey G.,
Susz B.P.
Publication year - 1961
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19610440531
Subject(s) - chemistry , benzophenone , benzoyl chloride , chloride , aluminium , aluminium chloride , friedel–crafts reaction , acyl chloride , medicinal chemistry , benzene , chlorine , polymer chemistry , organic chemistry , catalysis
Benzoyl chloride and AlC1 3 give an addition compound with a dative oxygenaluminium bond. The F RIEDEL‐CRAFTS synthesis of benzophenone from benzoyl chloride and benzene in the presence of Al 36 C1 3 is shown by the authors to give rise to a statistical repartition of the radioactive chlorine between the HC1 evolved and the addition compound of benzophenone and AlCl 3 .