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Etude préliminaire au dosage des éléments par activation aux neutrons, basé sur la formation d'isotopes à courte période: séparations rapides et détermination des pertes
Author(s) -
Monnier D.,
Haerdi W.,
Vogel J.
Publication year - 1961
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19610440402
Subject(s) - chemistry , cobalt , nuclear chemistry , radiochemistry , neutron activation , neutron activation analysis , aqueous two phase system , aqueous solution , extraction (chemistry) , inorganic chemistry , chromatography , neutron , physics , quantum mechanics
The authors submit a method for the rapid separation of cobalt by toluene extraction of its β‐nitroso‐α‐naphthol complex, with estimation of the losses involved. Iron, the chief element causing disturbance in assay by gamma spectrometry ( 60 Co) after activation, gives a complex with sodium fluoride‐acetate‐citrate in a medium at pH 5–6 and remains quantitatively in the aqueous phase. In this way it has been possible to separate 0,1 μg of cobalt in presence of 100 mg of iron. The estimation of losses is carried out by means of a radioactive tracer ( 58 Co), isotope of the element being assayed (cobalt 60 or 60 m). The time necessary for separation and estimation is about 20 min and would thus permit a cobalt assay based on that of the cobalt 60 m (periode 10,5 min) wich is formed by activation. A chemical method for the control of losses has also been studied.