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Zur Kenntnis der Hexaalkylbenzole. 1. Mitteilung. Anomale F RIEDEL ‐C RAFTS ‐Reaktionen von Hexaäthyl‐ und Hexamethylbenzol
Author(s) -
Hopff H.,
Wick A. K.
Publication year - 1960
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19600430604
Subject(s) - chemistry , hexa , alkyl , medicinal chemistry , stereochemistry , hexamethylbenzene , organic chemistry , benzene
An anomalous type of F RIEDEL ‐C RAFTS reaction was observed with hexaethyland hexamethylbenzene. With a number of acid chlorides and γ‐dicarboxylic anhydrides the reaction proceeded by elimination of an alkyl group with production of the corresponding pentaalkylphenyl ketones and γ‐pentaalkylbenzoyl acids respectively.