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Effet isotopique de l'hydrogène dans l'irradiation et la décomposition thermique du diphényle
Author(s) -
Rayroux J. M.,
Baertschi P.
Publication year - 1960
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19600430204
Subject(s) - chemistry , radiolysis , pyrolysis , nuclear chemistry , irradiation , thermal stability , radiochemistry , organic chemistry , radical , physics , nuclear physics
The radiation stability and the thermal stability of ordinary (C 12 H 10 ) and deutero (C 12 D 10 ) diphenyl have been measured and compared. Deuterodiphenyl is more stable than the ordinary diphenyl by a factor of about 2, for pyrolysis at 460°C as well as for radiolysis at 30–40°C and at 310°C. This difference is of practical importance for the consideration of deutero‐diphenyl as coolant for power reactors.

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